Removal of Copper ions from wastewater using Emulsion Liquid Membrane: Optimization and Performance Analysis

Authors

  • Sara Mobasser Department of Chemical Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran Author
  • Malihe Raji Department of Chemical Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran Author

Keywords:

Emulsion Liquid Membrane, Copper Ion removal, Industrial Wastewater Treatment, Heavy Metal Extraction

Abstract

Extraction using emulsion liquid membranes has recently become an area of rapid research interest due to its efficiency in the removal of heavy metal ions and toxic substances from industrial wastewater. This study is a comprehensive investigation for copper ion removal from wastewater using emulsion liquid membranes (ELM). Hydrochloric acid (HCl) was used as the internal phase, while di(2-ethylhexyl) phosphoric acid (D2EHPA) was used as the carrier and Span 80 as surfactant. In addition, sunflower oil was used as the organic phase. A number of significant parameters such as pH, mixing speed, and surfactant concentration, were evaluated to optimize copper extraction efficiency. The results show that the maximum amount of extraction was %96.31 which obtained under optimal conditions with a pH of 3.0, surfactant concentration of 2 V/V%, and a stirring speed of 180 rpm.

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Author Biographies

  • Sara Mobasser, Department of Chemical Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran

      

  • Malihe Raji, Department of Chemical Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran

      

References

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[3] H. Ma, K. E. Waters, and H. Wang, "A Review of Copper and Nickel Extraction from Wastewater by Emulsion Liquid Membrane (ELM)," Mining, Metallurgy & Exploration, vol. 40, no. 1, pp. 13-39, 2023.

[4] J. Mendil, A. Alalou, H. Mazouz, and M. H. Al-Dahhan, "Review of Emulsion Liquid Membrane for Heavy Metals Recovery from Wastewater/water: Stability, Efficiency, and Optimization," Chemical Engineering and Processing-Process Intensification, p. 109647, 2023.

[5] P. Davoodi-Nasab, A. Rahbar-Kelishami, and M. Raji-Asadabadi, "Fast and efficient chromium (VI) pertraction with Aliquat 336 in emulsion liquid membrane using sunflower oil as a high potential solvent," Desalination and Water Treatment, vol. 80, pp. 234-246, 2017.

[6] M. Raji, H. Abolghasemi, J. Safdari, and A. Kargari, "Pertraction of dysprosium from nitrate medium by emulsion liquid membrane containing mixed surfactant system," Chemical Engineering and Processing-Process Intensification, vol. 120, pp. 184-194, 2017.

[7] S. Zereshki, A. Shokri, and A. Karimi, "Application of a green emulsion liquid membrane for removing copper from contaminated aqueous solution: Extraction, stability, and breakage study using response surface methodology," Journal of Molecular Liquids, vol. 325, p. 115251, 2021.

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Published

2025-02-18

How to Cite

Removal of Copper ions from wastewater using Emulsion Liquid Membrane: Optimization and Performance Analysis. (2025). Development Engineering Conferences Center Articles Database, 2(7). https://pubs.bcnf.ir/index.php/Articles/article/view/361

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